catena-Poly[[(1,10-phenanthroline-κ2 N,N′)zinc]-μ-4-sulfonatobenzotriazolido-κ3 N 3,O:N 1]
نویسنده
چکیده
In the title complex, [Zn(C(6)H(3)N(3)O(3)S)(C(12)H(8)N(2))](n), the Zn(2+) cation is coordinated by two N atoms from two 4-sulfonato-benzotriazolide dianions, two N atoms from a 1,10-phenanthroline mol-ecule and a sulfonate O atom from a 4-sulfonato-benzotriazolide anion, displaying a distorted ZnN(4)O trigonal-bipyramidal geometry. Each 1,10-phenanthroline ligand displays a bidentate chelating coordinating mode and the 4-sulfonato-benzotriazolide ions act as μ(2)-bridges, linking different Zn(2+) cations into a chain along the b axis. The crystal structure is consolidated by C-H⋯O hydrogen-bonding inter-actions.
منابع مشابه
catena-Poly[[(1,10-phenanthroline)cadmium(II)]-μ-2-(1,3-benzimidazol-2-ylsulfanyl)acetato-κ3 N 1,O:N 3]
In title compound, [Cd(C(9)H(6)N(2)O(2)S)(C(12)H(8)N(2))](n), the Cd(II) atom is in a distorted tetra-gonal-pyramidal environment, coordinated by one chelating 1,10-phenanthroline ligand, one chelating 2-(1,3-benzimidazol-2-ylsulfan-yl)acetate (bia) ligand bound through one N atom and one O atom of the carboxyl group, and one N atom from a second bia ligand. Each bia ligand acts as bridge betwe...
متن کاملcatena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)lead(II)]-di-μ-2-hydroxybenzoato-κ3 O 1,O 1′:O 2;κ3 O 2:O 1,O 1′]. Corrigendum
A reference in the paper by Xuan & Zhao [Acta Cryst. (2007), E63, m2678] is replaced.[This corrects the article DOI: 10.1107/S1600536807045941.].
متن کاملcatena-Poly[[[(1,10-phenanthroline-κ2 N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ4 O 1:O 1′-μ-nitrato-κ3 O,O′:O] bis(1,10-phenanthroline)]
The title complex, [Pr(C(7)H(5)O(3))(2)(NO(3))(C(12)H(8)N(2))]·2C(12)H(8)N(2), has a polymeric chain structure, with two uncoordinated 1,10-phenanthroline mol-ecules in the lattice. The Pr(III) centre has a monocapped square-anti-prismatic coordination geometry, comprised of two N atoms from one chelating 1,10-phenanthroline ligand, four carboxyl-ate O atoms from four 4-hy-droxy-benzoate anions...
متن کاملcatena-Poly[[[diaqua(1,10-phenanthroline-κ2 N,N′)zinc]-μ-4-hydroxy-3-sulfonatobenzoato-κ2 O 3:O 1] sesquihydrate]
The 1,10-phenanthroline-chelated Zn atom in the polymeric title compound, {[Zn(C(7)H(4)O(6)S)(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), is connected to the sulfonate O atom of one 4-hy-droxy-3-sulfonato-benzoate dianion and to the carboxyl-ate O atom of another dianion. It is also coordinated by two water mol-ecules in an overall octa-hedral environment. The dianion links adjacent metal atoms int...
متن کاملcatena-Poly[[(1,10-phenanthroline-κ2 N,N′)praseodymium(III)]-di-μ-phenoxyacetato-κ4 O:O′-[(1,10-phenanthroline-κ2 N,N′)praseodymium(III)]-di-μ-phenoxyacetato-κ4 O:O′-di-μ-phenoxyacetato-κ3 O,O′:O;κ3 O:O,O′]
The title complex, [Pr(2)(C(8)H(7)O(3))(6)(C(12)H(8)N(2))(2)](n), which has an inversion centre midway between the two Pr(III) atoms of the structural unit, forms a one-dimensional polymer bridged alternately by either two bidentate, or two bidentate and two terdentate, phenoxy-acetate carboxyl-ate groups. Each Pr(III) atom is thus nine-coordinated by two N atoms of a 1,10-phenanthroline ligand...
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